“Mi Fuma il Cervello” self-portrait series of Alighiero Boetti: evaluation of a conservation and maintenance strategy based on sacrificial coatings
© The Author(s) 2017
Received: 6 February 2017
Accepted: 3 April 2017
Published: 17 May 2017
“Mi Fuma il Cervello” (“steaming brain”) is the iconic self-portrait of Alighiero Boetti, in which the artist is represented standing up while a copper hose lets water flow on his head. A hidden electric resistance heats the sculpture’s head so that the splashing water forms a dense vapour mist as it comes in contact with the hot metal surface. Such system is normally active only during museum exhibitions and determines critical conservation issues due to the inevitable formation of a thick and adherent calcareous deposit. Recently, the Fonderia Artistica Battaglia (Milan, Italy) conducted an extensive conservative intervention aimed at retrieving the original aesthetic features of the bronze surface and its artificial patina finishing. A conservation strategy was proposed based on the use of a superficial coating, to protect the surface and to ease the removal of the calcareous deposits in view of future cleaning operations. Three siliconic commercial paints were selected and preliminarily applied to specimens that simulate the actual alloy. The efficacy, compatibility and durability of the treatments were tested by accelerated ageing test based on combined thermal and wetting cycles, representative of the real working conditions. A multi-analytical diagnostic approach was followed for the evaluation of the coatings characteristics and performances before and after aging: stereomicroscopy, ESEM-EDX, VIS-Light spectrophotometry, micro-FTIR, electrochemical impedance spectroscopy (EIS). The research showed that from the aesthetic point of view all coatings induce only limited and rather comparable initial colour variations. The permanence of the treatments upon ageing, used as durability indicator, was assessed in all cases but the protective layers appeared damaged and no longer continuous over the metal surface. The best performing treatment was identified and further tested with respect to re-treatability. The results provide indications for the general conservation and maintenance protocol.
KeywordsBronze Bronze preservation Coating Electrochemical impedance spectroscopy Monitoring
“Mi Fuma il Cervello” (“steaming brain”) is the iconic bronze self-portrait of Alighiero Boetti, one of the most appreciated Italian conceptual artist mostly known for his series of embroidered pieces of art. The original concept of the self-portrait dates back to the seventies and it was finally realized for the 1993 Sonsbeek exhibition in Arnhem (The Netherlands). Ugo Vismara made the preliminary gypsum model of the artist himself at the Arnaldo Pomodoro Atelier in Milan. The first bronze statue of a seven-pieces series was then casted from it at Fonderia Artistica Battaglia 1 , with dimensions 205 × 90 × 60 cm .
The present investigation was carried out in the framework of an extensive conservative intervention of one of the statues, conducted by Fonderia Artistica Battaglia (Milan, Italy) in view of a major exhibition of Alighiero Boetti’s works housed by Galleria Stein in 2014–2015. The aim of the research was the definition of a general conservation protocol for cleaning, protection and for the maintenance of all the statues of the series.
As far as the protection is concerned, it is worth noting that no standards are currently available for the evaluation of transparent coating for metal surfaces of the cultural heritage . The general requirements for coatings applied on such surfaces include: aesthetic compatibility, reversibility, respect of the original material, efficacy and maintenance . Coatings are therefore required to induce minimal alteration to the colour and to the overall appearance of the treated substrates, thus preserving the original patina and the presence of corrosion layers. According to reversibility, the protective layer should be removable from the surface even after ageing. The applied product should also be as much effective as possible in reducing the degradation rate over time, thus ensuring an adequate long-term efficacy and maintenance . In the specific case of Boetti’s self-portrait, additional requirements arise from the very critical exhibit condition, which can enhance the degradation rate of the protective layers applied onto the surface. A suitable treatment should be able to resist to such conditions, and to be completely removed when it is no longer efficient. The protective materials therefore do not have to undergo chemical alteration because of the high working temperature. Unfortunately, high-temperature corrosion-resistant coatings  are mainly developed for industrial applications, e.g. gas turbine engines, and are generally unsuitable for the cultural heritage field, as they do not comply with the specific requirements.
A preliminary survey was therefore conducted among transparent paints available on the market and able to sustain working temperature up to 350 °C, which is higher than that of the statue. Three silicone-based commercial paints were selected and preliminary applied to specimens simulating the actual alloy and finishing of the statue. Such products are not specifically intended for the cultural heritage surfaces and their compatibility for this specific application had to be assessed. The aim of the research was to identify a sacrificial coating to reduce the risk of patina or sculptural detail losses, and to ease the deposits removal. For that it was necessary: (a) to assess the aesthetic compatibility of the coating; (b) to monitor its efficacy over time; and (c) to evaluate the reversibility upon ageing with respect to the ease of removal of the aged coating from the surface. The efficacy, compatibility, durability and reversibility were tested after accelerated ageing test based on combined thermal and wetting cycles, representative of the actual working conditions. A multi-analytical diagnostic approach was applied for the preliminary characterization and the monitoring through stereomicroscopy, SEM and colorimetric measurements. Coatings efficacy and durability were monitored by non-destructive in situ electrochemical impedance spectroscopy (EIS), used to evaluate the initial treatment efficacy and its durability with time. Such technique provides real time information about the degradation rate of the artefact following a non-invasive in situ approach.
Even though the actual exposition conditions of the series can be considered very challenging and rather far from those generally encountered on bronze statues exposed outdoor, the conservation and maintenance strategy here reported, based on the use of sacrificial protective layers, represents a suitable alternative also in more traditional conditions.
Composition of bronze samples (weight %)
Three commercial coatings were selected for the testing on the basis of their resistance to high temperature (up to 350 °C) and transparency, as reported in technical data sheets. Unfortunately, none of the coatings usually applied to bronze artworks can be used for comparison, as they are unsuitable for high temperature. The commercial products are supplied by Talken (color thermopaint heat resistant), Dupli-color (Supertherm spray) and Saratoga (happy color high temperature).
The coatings were applied by spraying in three layers. Each layer was applied after drying of the previous one. Following application, the silicon paints need proper curing to improve the adhesion with the metal substrate and to provide adequate protection, as stated in the technical datasheets. The recommended curing is 1 h at 150 °C for Dupli-color and Saratoga, whereas no indications are provided for Talken. Such a high curing temperature is not suitable in case of cultural heritage objects since it cannot be safely applied in situ or in normal restoration studio. The curing effects on coatings were therefore investigated also at lower temperature to evaluate compositional changes and corrosion protection resulting from the heat treatment. The following conditions were tested: (a) not cured; (b) cured at 50 °C for 20 h; (c) cured at 150 °C for 1 h. The compositional changes were studied on the products applied on microscopy glass slides while corrosion resistance was measured on bronze specimens. The 20-h curing at 50 °C was selected being more suitable for in situ treatments, e.g. by using portable IR-lamps. It was decided to use such curing methodology for the tests of coating performances on bronze specimens since it proved to be effective for the specific application (see “Results and discussion” section).
An accelerated ageing procedure was defined to induce a deterioration patterns on the specimens similar to the one occurring to the statue during exhibitions. The accelerated ageing procedure consisted in heating the samples up to 300 °C while pouring tap water continuously on the surface of the specimens, thus recreating the vapour mist and consequent formation of calcareous deposits. Tap water was used to simulate the most representative and stressing working condition, as it is the one normally available during exhibitions, and to promote the formation of the undesired calcareous deposits. The samples were artificially aged for 100 h, which typically corresponds to a 2-week exhibition period of the statue (6 days per week; 8 h per day).
After aging, the thick calcareous deposits were removed by poultice, using an aqueous solution of 10% EDTA supported by methylcellulose. The contact time of the poultice was 1 h and the application was repeated two times. After removal of each poultice, the surface was rinsed with demineralized water. All specimens were characterised before and after the application of the three products, after aging and after deposit removal. In addition, the reversibility of the treatment was evaluated on the best performing product by removing the coating after cleaning of the calcareous deposits with cotton swabs and acetone.
Labelling of the surface conditions
Not treated surface
Surface protected with a coating cured at 50 °C
Surface protected with a coating and artificially aged
Surface protected with a coating and aged. Calcareous deposit cleaned with EDTA poultice
Surface protected with a coating and aged. Calcareous deposit cleaned with EDTA poultice and coating removed with acetone
The photographic documentation of the specimens was made by a Canon Power Shot A2100 IS.
Stereomicroscopic observation was performed with a Leica M250C stereo microscope equipped with a Leica DFC290 digital camera for image acquisition.
Scanning electron microscopy with Energy Dispersive Spectroscopy (SEM–EDS) was performed by using a Zeiss EVO 50 EP instrument equipped with a LaB6 source and X-ray Oxford INCA 200-Pentafet LZ4 spectrometer.
Fourier transformed infrared analyses (FTIR) were performed with a Nicolet 6700 spectrophotometer coupled with a Nicolet Continuum FTIR microscope. Micro-samples of the coatings were analysed in diamond compression cells using an MCT detector, with spectral field 4000–600 cm−1.
Colorimetric measurements were performed with a Konica Minolta CM600D VIS light spectrometer to evaluate the aesthetic effect of treatments. The colorimetric coordinates were registered in the CIE L*a*b* colour reference space , 10 measurements were performed for each sample evenly distributed on the sample surface. Average values and standard deviations of L*, a* and b* parameters collected in SCI (specular component included) modality were calculated. The global colour variations, ΔE, were calculated according to the formula reported in the UNI EN-15886 standard .
Characteristics of soft mineral water
Temperature at the water source (°C)
pH at the temperature of the water source
Fixed residual at 180 °C (mg l−1)
Conductivity at 25 °C (μS cm−1)
Free CO2 (mg l−1)
Dissolved O2 (mg l−1)
Substances dissolved in soft mineral water (mg l−1)
Results and discussion
Effect of curing
As far as the coating corrosion protection is concerned, the results of Rp measurements are reported in Fig. 3. The initial value of Rp for untreated samples is, as expected, quite low, around 0.6 ± 0.5 Ω m2. This indicates that the artificial patina does not provide any protection to the bronze substrate. The increase of Rp for coatings without curing is moderate, between one and two orders of magnitude. The efficacy of the coating with 50 °C curing is greatly improved, Rp values being about 105 Ω m2. Since Rp values are inversely correlated to corrosion rate, the results suggest that the coatings cannot provide an effective protection against corrosion without a proper curing. As it can be observed, a 20-h curing at 50 °C leads to an increase of Rp of three to four orders of magnitude compared to the not cured ones, and therefore to a reduction of the corrosion rate of the same order of magnitude. Consequently, only a 50 °C curing treatment was considered for the rest of this study. Among the not cured specimens, the best performing product in terms of corrosion protection is Saratoga. Even though the primary purpose of the proposed coatings is not to provide protection against corrosion, to reduce the corrosion rate is always a desirable additional feature of a protective treatment.
Coating compatibility and influence on calcareous deposits
In terms of aesthetic compatibility of the coating, the macroscopic and stereomicroscopic observations of the surfaces do not reveal significant alterations of the surface appearance after application. All the morphological features previously discussed are preserved and only a moderate increase of the superficial gloss and of the colour saturation can be qualitatively assessed (Fig. 4, specimens labelled P). This corresponds to a slightly darker appearance of the treated surface to the naked eye.
Global colour changes calculated between the not treated surface and after coating application (NT-P), and between the not treated surface and after ageing and cleaning of the coating (NT-PAC)
The combined thermal and wet artificial ageing induced, as expected, the formation of calcareous deposits on the specimens, thus dramatically altering the surface appearance. A thick and rather homogeneous deposit can be observed on the sample treated with Talken (Fig. 4, specimens labelled PA). The deposit has a strong adhesion to the substrate and shows a light blue to green superficial appearance due the thick calcareous formation mixed with corrosion products. This is well described by the colorimetric measurements (Fig. 5, green dots): a sharp rise of the lightness (∆L = 21), associated to a significant reduction of the average red component (∆a = −9), which is greater than the pretty large standard deviation both in the red-green (a*) and yellow-blue (b) direction.
A diffused but not homogenous deposit is formed on Saratoga samples (Fig. 4, specimens labelled PA). In this case the ageing procedure developed an irregularly distributed deposit over the specimen, so that the bronze as well as the overlapped transparent coating can be observed throughout the few discontinuities of the deposit itself. The deposit shows lower adhesion to the substrate with respect to Talken specimen, so that it can be partly removed by mild mechanical actions. The warm superficial hue of the aged specimen is characterized also in this case by increased lightness (Fig. 5, green dots) due to the almost white deposit formed (∆L = 14), and reduction of the average red component (∆a = −6) less marked than for Talken but with a much lower standard deviation. The standard deviation in the yellow-blue component (b*) remains, instead, quite high.
The Dupli-color specimen shows the most irregular deposit after ageing. The calcareous encrustation only partially covers the substrate. Due to its limited thickness, the bronze remains still partly visible underneath (Fig. 4, specimens labelled PA). This corresponds to more limited variation of the colorimetric characteristics with respect to the other coatings. The average lightness increase is almost negligible (Fig. 5, green dots), although with much larger standard deviation than the other coatings, due to the discontinuous presence of the deposit. The main effect is the reduction of the average red component (∆a = −5) also in this case. The overall results indicate that the presence of Dupli-color is associated with a reduced formation of the calcareous deposit over the bronze surface, compared to the other treatments.
Removal of calcareous deposits
Qualitative evaluation of the ease of the cleaning procedure was performed in collaboration with the restorer. The same cleaning methodology was applied to all the aged samples. The addition of the coating facilitates the removal of the calcareous deposits, allowing a less invasive and more cost-effective cleaning operation. As a matter of fact, the adhesion of the deposits, assessed during cleaning, is reduced and the presence of a sacrificial intermediate layer widens the range of suitable cleaning procedures. Therefore, chemical treatments, such as the one previously described with EDTA poultice, can be applied without removing the patina.
Talken (Fig. 7) shows residual presence of the deposit with needle-like crystals (LD) where the cleaning procedure failed to remove completely the deposit. The ESEM analysis detected also several discontinuities in the coating, which has been partially detached or removed from the substrate. In such areas, the bronze, no longer protected by the coating, is exposed and can be identified by its bright colour in back-scattered analysis mode. The Dupli-color layer after ageing is highly damaged and its surface continuity is therefore compromised (Fig. 7). Diffused fissures and micro-cracks cross the protected surface and fragments of the coatings are detached from the substrate. The ESEM analysis also highlights the presence of thin residues of the deposit (Fig. 7, LD). Some residual crystals from the deposit are still present also on the Saratoga specimen (Fig. 7, LC), which developed a rather different deterioration morphology after ageing. A pattern of bubble-like blistering is formed, leading to localized detachments of the coating. Moreover, where the blisters are partially or completely cracked (Fig. 7, white arrow), the coating no longer forms a continuous layer.
Colorimetric characterization allowed to additionally assess the compatibility of the aged treatments and to evaluate the coating efficacy in increasing the deposit removal, thus acting as an effective protective sacrificial layer. Specimens treated with Talken and Saratoga paints after the deposit cleaning (PAC) get back to L* values close to those of NT (untreated) and P (protected) surfaces (Fig. 5, cyan dots). The same applies to the a* coordinate. It has to be noted that in this case the difference with the corresponding NT (untreated) and P (protected) values remains a little bit greater than standard deviations. The dispersion of colour values remains pretty large for Talken, in particular for L* values. On the other hand, the standard deviations of Saratoga are reduced after cleaning to values similar to those of the NT (untreated) and P (protected) surface. This is due to better removal of the deposits on Saratoga treated specimens, whereas some residues are left on Talken.
The specimen treated with Dupli-color paint after deposit cleaning (PAC) underwent the most relevant colour change. This is due to a decrease of lightness associated to a peculiar and intense reduction of b*. In addition, a moderate reduction of the a* coordinate is observed as for the other coatings.
The overall colour results after ageing and cleaning allow to state that the Saratoga specimen shows the last relevant colour alteration, which consists mainly in reduced saturation of the hue with respect to the not treated one. The global colour changes after cleaning (PAC) with respect to the initial not treated bronze surfaces (NT) are reported in Table 5. Talken and Saratoga show similar results, whereas the variation induced by Dupli-color is considerably higher.
Corrosion protection, stability and durability of treatments
Even though corrosion protection is not the main goal of the proposed “sacrificial” coatings, the reduction of the corrosion rate would be a highly desirable additional feature of the treatment. As previously commented, all proposed coatings provide good initial protection of the specimens against atmospheric corrosion (Fig. 3). However, it is worth reminding that the real statues are subjected to very critical conditions during exhibitions that may result in rapid deterioration of the coatings. Differences in terms of corrosion protection after aging are therefore crucial for the selection of the best performing coating: a high final protection outcome is not only desirable, but is also correlated to stability and durability of the applied product.
After accelerated aging, the three proposed treatments show quite a different performance despite the very similar initial behaviour. They all present marked reduction of Rp values, that indicates reduction of the protection provided by the coating. Among all, Saratoga shows the lowest loss of protection, notwithstanding the surface pattern of cracked bubbles observed by SEM. As a matter of fact, although its surface continuity appears compromised, Rp values of aged Saratoga paint is still about two orders of magnitude higher than the untreated samples. Dupli-color paint provides lower protection against corrosion after aging compared to Saratoga, showing Rp values that are only one order of magnitude higher than the untreated surface. The worst performance is given by Talken, which presents Rp values after aging very close to the untreated samples, indicating that this type of coating does not provide a durable protection against corrosion after aging.
Selection of the most suitable coating
Considering the overall results, Saratoga was identified as the most suitable sacrificial treatment. It showed the best performances in term of corrosion protection and durability, as well as an overall good aesthetic compatibility in terms of global colour variation. Also Talken can be considered a suitable choice, however it was not selected considering its reduced corrosion protection properties after aging compared with Saratoga. On the other hand, Dupli-color has to be discarded because of its low durability with respect to corrosion protection and to low chemical stability under severe aging condition. Furthermore, despite the apparent reduction of the deposit formation, that was very efficiently removed from the surface, it displayed low aesthetic compatibility as it underwent the most significant colour changes after aging and deposit removal.
Check of the reversibility of the best performing coating
As previously discussed, reversibility in terms of possibility to completely remove a coating without damaging the substrate is a highly desirable requirement, although not always achievable, for any surface protection treatment of the cultural heritage. This is even more important in the case of a sacrificial layer, like the one proposed in this work, which is meant to be reapplied several times during the life of the artwork. Colorimetric and ESEM analyses have been performed in order to evaluate the removal efficacy of the aged coating.
The colorimetric characterisation of the surface after the removal of the aged and cleaned Saratoga paint (R) shows that the global colour change with respect to the untreated surface is very low (ΔE = 2.0). This value is significantly lower than the one calculated between the untreated (NT) and the aged and cleaned coating (PAC), as previously discussed (Table 5). This last is therefore mainly due to the alteration of the coating itself and to the minor contribution of the residual deposit.
The conservation of Alighiero Boetti’s self-portrait series presents very severe problems. In order to reduce the possible damage related to the periodic cleaning operations, the use of a sacrificial layer as part of the maintenance strategy has been proposed. Three transparent commercial paints for high temperature applications, but not specifically intended for cultural heritage surfaces, have been evaluated with respect to their overall compatibility, durability, efficacy after ageing and re-treatability. The selected coatings require a high temperature curing (around 150 °C) to ensure the best performances in working conditions. Preliminary tests were performed on not cured and on low temperature cured (50 °C) specimens in order to define a sustainable methodology that could be applied also in actual museum conditions. Results confirmed that curing is necessary, but it can be conducted even at low temperatures without hindering the paint performances.
According to the conservation requirements, the overall results indicate that Saratoga and Talken paints are suitable for the specific application. On the other hand, Dupli-color was discarded because of its chemical alteration, reduced compatibility and extremely low corrosion protection after aging.
Saratoga was identified as the best performing material due to its higher durability and better performance in terms of corrosion protection after aging compared with the other products. The selected paint also fulfilled the re-treatability requirement as it proved to be completely removable from the substrate without damaging the surface. Moreover, the removal operation can be easily carried out by means of an organic solvent following a cost-effective and low time-consuming methodology. In addition, the use of a sacrificial coating resulted convenient from the operative point of view since it facilitates the cleaning of the calcareous deposits. The proposed approach can therefore be implemented within the general maintenance protocol for the preservation of the complete series of portraits. In addition, a similar approach based on the use of sacrificial protective layers can also be considered as valid conservation strategy in case of more traditional works of art and in presence of less aggressive exposure conditions.
DG and SG conceived the study, performed part of the analyses, carried out the interpretation of the results and drafted the manuscript. BM prepared the specimens, carried out the treatments, cleaning and removal operations. EG and ST contributed to the electrochemical analysis, the interpretation of the data and critically reviewed the manuscript. LR performed part of the analyses and participated in the interpretation of the results. PL and LT participated in the data interpretation and critically reviewed the manuscript. All authors read and approved the final manuscript.
The authors declare that they have no competing interests.
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