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Table 1 Bronze-like covering: results of the PLM and SEM-EXD investigation on inorganic pigments

From: Recovery and examination of sculpture group Fugitive Slaveby V. Beklemishev

Sample

Layer

Elements detected by SEM-EDX

Suggested pigments and minerals

Bright

lower white layer

Ca, S

gypsum

lower dark brown layer

Si, Fe, Ca, S, K

mixture of gypsum and iron earth pigment

orange layer

Pb

lead red

dark brown layer

Si, Al, Fe, Ca, S, Mg, K

mixture of gypsum and iron earth pigment

bright orange chips

Cu

copper filings

uppermost very thin layer

Cu, As

copper arsenic

Dark

lower white layer

Ca, S

gypsum

lower dark brown layer

Si, Fe, Ca, S, K

mixture of gypsum and iron earth pigment

orange layer

Pb

lead red

dark brown layer

Si, Al, Fe, Ca, S, Mg, K

mixture of gypsum and iron earth pigment

bright orange of chips

Cu

copper filings

intermediate very thin layer

Cu, As

copper arsenic

thick dark brown layer

Si, Al, Fe, Ca, S, Mg, K

mixture of gypsum and iron earth pigment

orange layer with white inclusions

Pb

mixture of lead red and white lead

bright orange of chips

Cu

copper filings

upper dark brown layer

Si, Al, Fe, Ca, S, Mg, K

mixture of gypsum and iron earth pigment

uppermost very thin layer

Cu, As

copper arsenic

  1. For each sample, the layers are discussed from bottom to top.