Test number | Sample | Wire temperature °C | Rate and final temperature °C | Mode | Retention time in minutes | MS peaks (relative abundance) | Best match in NIST library |
---|---|---|---|---|---|---|---|
Test 2 14/06 | Interior upholstery | 770 | 10 min−1 290 for 10 min | Split | 24.56 | 41 (42), 43 (53), 57 (73), 69 (71), 70 (55), 71 (52), 149 (100) | Nist 87687: 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester |
Test 3 18/06 | Interior upholstery | 770 | 10 min−1 hold at 290 for 10 min | Split | 19.88 | 41 (33), 57 (17), 149 (100), 150 (10) | Nist 87196: 1,2-benzenedicarboxylic acid, butyl octyl ester |
20.03 | 41 (82), 43 (60), 55 (100), 57 (42), 69 (76), 74 (39), 81 (33), 83 (38) | Nist 16077: 9-octadecenoic acid (Z)-, methyl ester | |||||
24.55 | 41 (60), 43 (79), 57 (100), 70 (49), 71 (64), 149 (100), 167 (27) | Nist 87687: 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester | |||||
24.58 | 41 (51), 43 (67), 55 (47), 57 (100), 70 (48), 71 (56), 149 (79), 167 (22) | Nist 28948: octane 1 1′-oxybis- | |||||
26.17 | 43 (43), 57 (100), 69 (20), 70 (22), 73 (21), 99 (24), 127 (22), 172 (36) | Nist 21609: hexanoic acid, 2-ethyl-, 1,2-ethanediylbis (oxy-2,1-ethanediyl) ester | |||||
Test 5 18/06 | Interior upholstery | 480 | 10 min−1 hold at 290 for 10 min | Splitless | 5.96 | 41 (100), 42 (32), 43 (93), 55 (86), 56 (74), 57 (76), 69 (37), 70 (43), 83 (18), 84 (14) | Nist 2347: 2-tridecene, (Z)- |
7.43 | 41 (100), 42 (30), 43 (95), 55 (96), 56 (75), 57 (65), 69 (48), 70 (48), 83 (30), 84 (21) | Nist 2347: 2-tridecene, (Z)- | |||||
8.9 | 41 (48), 43 (84), 55 (30), 57 (100), 71 (39), 85 (22) | Nist 19943: heptadecane, 2,6-dimethyl- | |||||
10.34 | 41 (100), 43 (100), 55 (100), 56 (74), 57 (86), 69 (56), 70 (49), 83 (40), 97 (31) | Nist 2322: 3-tetradecene, (Z)- | |||||
11.679 | 41 (78), 43 (100), 55 (75), 56 (49), 57 (100), 69 (37), 70 (31), 71 (37), 83 (31), 97 (25) | Nist 2322: 3-tetradecene, (Z)- | |||||
12.95 | 41 (92), 43 (100), 55 (100), 56 (59), 57 (82), 69 (49), 70 (36), 71 (37), 83 (42), 97 (36) | Nist 16398: 7-hexadecene, (Z)- | |||||
Test 6 18/06 | Commercial shellac | 480 | 10 min−1 290 for 10 min | Splitless | 10.34 | 41 (86), 43 (100), 55 (82), 56 (56), 57 (100), 69 (43), 70 (40), 71 (32), 83 (31) | Nist 2322: 3-tetradecene, (Z)- |
11.7 | 41 (91), 43 (80), 55 (100), 56 (56), 57 (65), 69 (53), 70 (40), 83 (39), 97 (30) | Nist 2322: 3-tetradecene, (Z)- | |||||
12.95 | 41 (90), 43 (94), 55 (100), 56 (61), 57 (83), 69 (58), 70 (44), 83 (45), 97 (39) | Nist 16398: 7-hexadecene, (Z)- | |||||
15.96 | 41 (77), 43 (50), 55 (100), 60 (56), 69 (47), 73 (59), 83 (38), 111 (29) | Nist 30881: 9-oxononanoic acid | |||||
19.53 | 41 (54), 43 (35), 55 (100), 56 (56), 67 (36), 69 (25), 84 (46), 85 (66), 113 (25) | Nist 40947: 2-oxepanone, 7-hexyl- | |||||
19.68 | 41 (82), 43 (100), 55 (89), 57 (84), 60 (96), 69 (46), 71 (39), 73 (80) | Nist 7874: N-hexadecanoic acid | |||||
20.53 | 41 (68), 43 (58), 55 (92), 57 (51), 67 (66), 69 (53), 73 (62), 85 (43), 113 (100) | Octadecanoic acid, 6-hydroxy-, methyl ester | |||||
24.13 | 41 (83), 43 (62), 55 (68), 67 (53), 77 (64), 79 (51), 91 (100), 93 (45), 105 (54), 117 (84), 131 (67), 145 (34), 173 (35) | Nist 85035: 1,8-nonadien-3-yne, 2,8-dimethyl-7-methylene- | |||||
Test 7 18/06 | Interior upholstery | 770 | 15 min−1 hold at 290 for 8 min | Splitless | 5.24 | 41 (35), 42 (62), 43 (26), 55 (100),69 (23), 98 (28) | Nist 16302: Cyclohexanone |
8.99 | 41 (55), 43 (84), 55 (42), 57 (100), 71 (42) | Nist: 3-tetradecene, (Z)- | |||||
9.84 | 41 (45), 43 (79), 55 (36), 57 (100), 71 (45) | Nist 16015: 3-hexadecene, (Z)- | |||||
10.5 | 43 (29), 50 (60), 74 (24), 76 (85), 104 (100) | Nist 55191: phthalic anhydride | |||||
10.67 | 41 (89), 43 (100), 55 (100), 56 (56), 57 (83), 69 (60), 70 (43), 71 (39), 83 (48), 97 (43), 111 (20) | Nist 5151: E-14-hexadecenal | |||||
14.37 | 41 (77), 43 (100), 55 (80), 57 (80), 60 (94), 69 (40), 71 (36), 73 (77) | Nist 7874: N-hexadecanoic acid | |||||
15.13 | 43 (28), 50 (25), 65 (27), 76 (31), 104 (21), 149 (100) | Benzoic acid 2-(1-oxopropyl)- | |||||
15.57 | 41 (74), 43 (100), 55 (79), 57 (82), 60 (83), 69 (43), 71 (38), 73 (74) | Nist 7876: octadecanoic acid | |||||
Test 8 29/06 | Interior upholstery | 770 | 10 min−1 hold at 290 for 10 min | Splitless | 19.88 | 41 (24), 56 (13), 57 (15), 65 (11), 76 (11), 149 (100), 150 (10) | Dibutyl phthalate |
20.04 | 41 (73), 43 (64), 55 (100), 56 (30), 57 (46), 67 (47), 69 (66), 74 (43) | Nist 16077: 9-octadecenoic acid (z)-, methyl ester | |||||
24.55 | 41 (38), 43 (43), 55 (32), 57 (74), 70 (40), 71 (48), 149 (100), 167 (33) | Nist 87687: 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester | |||||
26.18 | 41 (23), 43 (35), 55 (24), 57 (100), 70 (17), 73 (27), 99 (22), 127 (27), 172 (44) | Nist 21609: hexanoic acid, 2-ethyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester | |||||
Test 9 29/06 | Interior upholstery | 770 | 10 min−1 hold at 290 for 10 min | Splitless | 9.01 | 40 (34), 43 (46), 44 (27), 50 (27), 51 (45), 77 (87), 105 (100), 120 (24) | Acetophenone |
13.82 | 50 (64), 74 (26), 76 (98), 104 (100) | Nist 55191: phthalic anhydride | |||||
19.67 | 41 (79), 43 (100), 55 (75), 57 (83), 60 (100), 69 (40), 71 (35), 73 (82) | Nist 7874: N-hexadecanoic acid | |||||
21.44 | 41 (73), 43 (100), 55 (78), 57 (57), 60 (100), 69 (48), 71 (39), 73 (64) | Nist 7874: N-hexadecanoic acid | |||||
24.55 | 41 (55), 43 (70), 55 (45), 57 (88), 70 (47), 71 (54), 149 (100), 167 (33) | Nist 87687: 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester | |||||
Test 10 29/06 | Standard: Polyethylene EC 680 Batch 0430 | 770 | 10 min−1 hold at 290 for 10 min | Splitless | 16.37 | 41 (66), 43 (98), 55 (69), 57 (100), 69 (40), 71 (51) | Hexadecane, 1,1-bis(dodecyloxy)- |