Skip to main content

Table 1 List of elements identified with FE-SEM-EDX in the different layers

From: The young Van Dyck’s fingerprint: a technical approach to assess the authenticity of a disputed painting

Sample

Layers

Elements detected

Pigments and fillers implied

S1–S3

Ground

Ca, Fe, Al, Si, Pb, K, Hg

Calcite, iron- and silica-rich red earths, lead white and vermilion

S1–S3

Priming

Pb, Ca

Lead white and calcite

S2

Red cloak

L1

Ca, Fe, Al, Si, Pb, K

Calcite, iron- and silica-rich red earths and lead white

L2

Ca, Fe, Al, Si, Pb, K, Hg

Calcite, iron- and silica-rich red eaths, lead white and vermilion

L3

Ca, Fe, Al, Si, P, S, K

Red lake and iron- and silica-rich red earths

S3

Blue sky

Ca, K, Fe, Co, Ni, As, Al, Si, Pb

Calcite, lead white and smalt

S1

Flesh tones (shadow)

Ca, K, Mn, Fe, Al, Si, Pb, K, Hg

Calcite, lead white, iron- and silica-rich red earths, manganese-based brown earths and vermilion

  1. The major elements identified are indicated in italic