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Table 3 Analytical techniques used to identify the pigments of the Book of Hours Cofre n.º 31

From: Colour identification, degradation processes and findings in a fifteenth-century Book of Hours: the case study of Cofre n.º 31 from Mafra National Palace

Colours

Identification

Analytical techniques

Pigments

µ-EDXRF

FORS

µ-Raman

µ-FTIR

Optical microscopy

Yellows

Lead–tin yellow type I: Pb2SnO4

  

Mosaic gold: SnS2

 

  

Greens

Malachite: Cu2CO3(OH)2

  

 

Organic lake

    

Lead–tin yellow (mixed with malachite)

    

Blues

Lapis lazuli: Na8(Al6SiO24)S8

 

Azurite: 2CuCO3–Cu(OH)2

 

Indigo: C16H10N2O2

  

  

Orange

Minium: Pb3O4

  

Reds

Vermilion: HgS

   

Organic lake

    

Pinks

Brazilwood lake

 

   

Lead white (mixed with brazilwood)

    

White

Lead white: [2PbCO3·Pb(OH)2]

    

Black

Carbon black (C)

  

  

Grey

Mixtures

    

Purples

Mixtures

    

Browns

Mixtures

    

Gold

Gold leaf (Au)

   

Gold powder (Au)

   

Silver (darkened)

Silver (Ag)

   

Additives

Calcium carbonate: CaCO3

  

 

Gypsum: 2H2O·CaSO4

  

 

Protein/polysaccharide bindings