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Table 4 Raman spectroscopy characteristics of pigments in different colors

From: Guangzhou Tongcao painting in late China Qing Dynasty (1840–1912 AD): technology revealed by analytical approaches

Color

Raman shift (cm−1)

Pigment identified

Detection points

Black

1324, 1596

Carbon black

Number 4

Yellow

1431, 1595, 1627

Gamboge

Number 7, 8, 9 and 16

Blue

259, 548, 808, 1096, 1355, 1645

Ultramarine blue

Number 1, 2, 13 &15

White

153, 280, 711, 1048, 1085

Calcite and lead white

Number 6 and 10

Green (Bright)

106, 119, 152, 172, 216, 240, 291, 323, 370, 431, 492, 538, 681, 755, 842, 950, 1438, 1563

Emerald green

Number 3

Green (Dark)

176, 217, 278, 369, 536, 952, 1336, 1595, 2093, 2156

The mixture of prussian blue, emerald green and carbon black

Number 11

Red

121, 151, 223, 314, 389, 548

Red lead

Number 5, 12 and 14