AMNH Catalog No. | Sample | Description | SEM/EDS Results* | Transmission FTIR and Raman Results |
---|---|---|---|---|
16/565 | S3 | Green paint over tan from face of bear holding killer whale | Gypsum, calcite, barite, traces of Fe-rich compounds [layer 2, green paint] / Lead white, barite, traces of Fe- and Ca-rich compounds [layer 1, tan paint] | Hydrocerussite, gypsum, calcite, barite, quartz, Prussian blue [FTIR] |
S4 | Green paint from ear of bear at top of pole | Calcite, barite, traces of Fe-oxides-hydroxides, lead white, lead chloride, fluorite [layer 1, green paint] | Gypsum, calcite, barite, quartz, Prussian blue [FTIR] | |
16/566 | S2 | Green paint over tan from human face at bottom of pole | Lead carbonate [layer 3, above green paint] / Calcite, traces of barite and Fe-rich compounds [layer 2, green paint] / Lead white, barite, traces of calcite, quartz, and Fe-rich compounds [layer 1, tan paint] | Gypsum, calcite, barite, quartz, Prussian blue [FTIR] |
16/567 | S4 | Darker green paint from leg of frog | Lead sulfate [layer 2, above green paint] / Calcite, barite, traces of silicates, Fe-, Zn-, and Pb-rich compounds [layer 1, green paint] | Gypsum, calcite, barite, quartz, Prussian blue [FTIR] |
S5 | Lighter green paint from leg of frog | Lead white, calcite, barite, traces of Mg-, Al-, Si-, K-, and Fe-rich compounds [layer 1, green paint] | Hydrocerussite, gypsum, calcite, barite, quartz, Prussian blue [FTIR] | |
16/568 | S4 | Red paint from woodpecker at top of pole, “intact” area | Vermilion [layer 2, red paint] / Vermilion, lead white, barite, traces of Fe-rich compounds [layer 1, red paint] | Hydrocerussite, cerussite, barite, starch [FTIR] / Vermilion [Raman] |
S5 | Red paint over filled crack from woodpecker at top of pole, “disturbed” area | Vermilion, lead white, barite, traces of gypsum and iron oxides/hydroxides [layer 1, red paint] | Hydrocerussite, cerussite, gypsum, barite, starch [FTIR] / Vermilion [Raman] | |
S6 | Black paint from bear’s eyebrow, “intact” area | Carbon black, gypsum, calcite, Fe-oxides/hydroxides [layer 2, black paint] / Carbon black, lead chloride, calcite, barite, quartz, alumina, traces of Fe- and Zn-rich compounds [layer 1, black paint] | Hydrocerussite, gypsum, calcite, barite, quartz [FTIR] / Carbon-based black [Raman] | |
S7 | Black paint over filled crack from bear’s eyebrow, “disturbed” area | Carbon black, calcite, quartz, alumina [layer 2, black paint] / Carbon black, bone or ivory black, zinc sulfide, calcite, barite, lead white, traces of Fe-rich compounds [layer 1, black paint] | Hydrocerussite, gypsum, calcite, barite, quartz, starch [FTIR] / Carbon-based black [Raman] | |
S8 | Green paint from eye of standing wolf/bear | Calcium sulfate, possibly gypsum [layer 2, above green paint] / Calcite, barite, traces of Fe-rich compounds [layer 1, green paint] | Gypsum, calcite, barite, quartz, Prussian blue [FTIR] / Calcite, barite, Prussian blue [Raman] | |
S9 | Green paint from eye of human figure | Calcium sulfate, possibly gypsum [layer 2, above green paint] / Calcite, barite, Prussian blue, traces of Pb-rich compounds, possibly lead chlorides [layer 1, green paint] | Gypsum, calcite, barite, quartz, Prussian blue [FTIR] / Calcite, barite, Prussian blue [Raman] |