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Table 3 Elements present in the manuscript of Mateo Pumacahua (eighteenth century)

From: XRF elemental analysis of inks in South American manuscripts from 1779 to 1825

Element

Average concentration (ppm)

Olympus Delta Premium DP6000

LOD (ppm)d

Inka

Stampb

Paperc

Ca

21,069 ± 5448

23,047 ± 2777

26,341 ± 3570

10–35

S

30,966 ± 17,124

13,332 ± 2555

7316 ± 3632

50–150

Fe

6324 ± 3245

2692 ± 456

1407 ± 348

5–20

Cl

3002 ± 780

3148 ± 453

4896 ± 1476

K

2894 ± 1131

1600 ± 501

1336 ± 270

20–50

Mn

251 ± 12

258 ± 13

254 ± 7

3–7

Cr

91 ± 7

100 ± 6

99 ± 3

2–9

Zn

79 ± 32

110 ± 6

102 ± 12

1–3

Ti

43 ± 14

71 ± 7

76 ± 40

5–10

Cu

29 ± 22

43 ± 11

17 ± 11

2–6

V

23 ± 3

30 ± 3

28 ± 3

4–10

Ag

20 ± 3

23 ± 5

19 ± 3

5–12

Sr

13 ± 4

16 ± 3

15 ± 4

1–2

Pb

7.6 ± 3

53 ± 13

6.8 ± 2.5

1–4

As

4.3 ± 1.1

20 ± 5

4.3 ± 1.4

1–3

Rb

3.9 ± 0.8

4 ± 1

3.8 ± 0.4

1–2

Mo

4.2 ± 0.6

3 ± 2

3.6 ± 0.4

1–2

  1. an = 40
  2. bn = 6
  3. cn = 5; n = number of analyzed points; x̅ = Average; SD = Standard Deviation
  4. d[27]