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Table 1 Summary of FORS and XRF results obtained on the blue areas of the illuminated manuscript fragments analyzed

From: Use of standard analytical tools to detect small amounts of smalt in the presence of ultramarine as observed in 15th-century Venetian illuminated manuscripts

Title

Area

‘Inside’

‘Outside’

FORS

XRF—Major, minor, (trace) signal

Pigments

Dormition of the Virgin

Initial G

 

✓

max refl 476 nm, min refl 600 nm, abs 1452 nm

Si, Pb, K, Al, Fe, Co, S (Cu, Ti, Mg, Na)

Ultramarine, smalt, lead white

Background to text

 

✓

max refl 462 nm, min refl 600 nm

Si, Pb, K, Fe, Al, Co, S, Cl? (Ti, Mg, Na)

Ultramarine, smalt, lead white

Sky

✓

 

max refl 471 nm, min refl 594 nm

Pb, Si, Al, K, Fe, Co, (Na, Mg, Ti)

Ultramarine, smalt, lead white

Book

✓

 

n/a

Si, Pb, K, Al, Cl? (Na)

Ultramarine, lead white

Virgin’s robe

✓

 

max refl 455 nm, min refl 600 nm, abs band 1452 nm

Pb, Si, K, Al, Cl? (Na, Ti?)

Ultramarine, lead white

St Blaise

Dark blue in border

 

✓

max refl 469 nm, min refl 597 nm, slight abs 1450 nm

Pb, Fe, Co, K, Si, (Ti, As, Al?)

Ultramarine, smalt, lead white

Light blue in border

 

✓

max refl 471 nm, min refl 594 nm

Pb, Fe, Co, Al, Si (K?, Ti?)

Ultramarine, smalt, lead white

Dark blue in robe

✓

 

max refl 469 nm, min refl 593 nm

Pb, Fe, Co, K, Si (Ti)

Ultramarine, smalt, lead white

Light blue in robe

✓

 

max refl 468 nm, min refl 594 nm, abs 1452 nm

Pb, Fe, Co, K, Si, Hg, (Ti?)

Ultramarine, smalt, lead white, vermilion (likely on verso)

Blue on glove

✓

 

n/a

Pb, Fe, Co, K (Ti)

Ultramarine, smalt, lead white

St Jerome

Dark blue in border

 

✓

max refl 470 nm, min refl 597 nm

Pb, Fe. Co, K, Si (Al, Ti)

Ultramarine, smalt, lead white

Light blue in border

 

✓

max refl 465 nm, min refl 597 nm, slight abs 1451 nm

Pb, Fe. Co, K, Si (Ti)

Ultramarine, smalt, lead white

Jerome’s robe lining

✓

 

max refl 468 nm, min refl 584 nm, abs 1451 nm

Pb, K, Si

Ultramarine, lead white

St Lawrence

Dark blue in border

 

✓

max refl 466 nm, min refl 595 nm, refl inflection 711 nm, abs 1451 nm

Pb, Fe, Ca, Co, K, Au, Hg, Si (Cu, Ti)

Ultramarine, smalt, lead white

Light blue in border

 

✓

max refl 469 nm, min refl 595 nm, refl inflection 700 nm

Pb, Fe, Co, Ca, K, Cu, Si

Ultramarine, smalt, lead white

Dark blue collar

✓

 

max refl 470 nm, min refl 601 nm, refl inflection 711 nm

Ca, Fe, Ag, Co, K, Si (Cu, Pb, Ti)

Ultramarine, smalt, silver

Dark blue robe design

✓

 

max refl 488 nm, min refl 590 nm, refl inflection 695 nm

Cu, Ca, Fe, K, Au, Hg, Co, Si (Pb, Ti)

Ultramarine, smalt, gold on copper green

Initial G with The Nativity of the Virgin Mary

Dark blue in border

 

✓

max refl 466 nm, min refl 592 nm, abs 1451 nm

Pb, K, Fe, Co, Si (Ti, Mn, Al); one spot with Hg from nearby red field

Ultramarine, smalt, lead white

Light blue in initial

 

✓

n/a

Pb, Fe, Co, K, Si (Ti); Hg (one spot)

Ultramarine, smalt, lead white (vermilion likely from verso)

Virgin’s robe

✓

 

max refl 465 nm, min refl 597 nm, abs 1451 nm

Pb, Fe, Co, K, Si (Ti, Sn?)

Ultramarine, smalt, lead white

Camaldolese Saint

Dark blue of initial

 

✓

max refl 469 nm, min refl 583 nm, slight abs 1449 nm

Pb, K, Co, Si (Al, Ti)

Ultramarine, smalt, lead white

Light blue of initial

 

✓

n/a

Pb, Hg, K, Co, Si (Al)

Ultramarine, smalt, lead white (vermilion likely from verso)

  1. Reflectance spectral features and chemical elements due solely to the parchment support are not listed