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Table 2 Weight % by element (average +/- standard deviation) for each pigment class used to generate synthetic spectra

From: Neural network-based classification of X-ray fluorescence spectra of artists’ pigments: an approach leveraging a synthetic dataset created using the fundamental parameters method

Pigment class

H

C

O

Na

Mg

Al

Si

P

S

Cl

K

Ca

Ti

Arsenic sulphides

35 ± 6

Bone black

0 ± 0

10 ± 0

36 ± 1

3 ± 2

16 ± 0

35 ± 1

Chalk

12 ± 0

48 ± 0

40 ± 0

Copper pigments

2 ± 2

8 ± 3

42 ± 9

Gold

Green earth

0 ± 0

44 ± 1

0 ± 0

3 ± 1

3 ± 2

26 ± 3

0 ± 0

6 ± 2

2 ± 2

1 ± 1

Gypsum

2 ± 0

56 ± 0

19 ± 0

23 ± 0

Iron earth pigments

1 ± 1

1 ± 2

47 ± 5

1 ± 3

6 ± 6

16 ± 11

4 ± 6

1 ± 1

8 ± 10

0 ± 1

Lead–tin yellow

13 ± 3

3 ± 4

Lead pigments

0 ± 0

2 ± 2

13 ± 4

Naples yellow

15 ± 0

Smalt

44 ± 2

0 ± 0

0 ± 0

33 ± 2

5 ± 5

1 ± 1

Ultramarine

35 ± 12

11 ± 2

0 ± 0

17 ± 1

22 ± 2

6 ± 2

1 ± 1

3 ± 3

4 ± 2

Umber

1 ± 1

1 ± 2

47 ± 5

1 ± 0

4 ± 2

15 ± 6

0 ± 0

2 ± 3

1 ± 0

2 ± 1

Vermilion

14 ± 0

Pigment class

Mn

Fe

Co

Ni

Cu

As

Ag

Sn

Sb

Au

Hg

Pb

Bi

Arsenic sulphides

65 ± 6

Bone black

Chalk

Copper pigments

48 ± 14

Gold

0 ± 1

1 ± 1

99 ± 2

Green earth

0 ± 0

16 ± 2

Gypsum

Iron earth pigments

0 ± 0

16 ± 13

Lead–tin yellow

16 ± 6

68 ± 4

Lead pigments

85 ± 8

Naples yellow

32 ± 0

54 ± 0

Smalt

3 ± 1

4 ± 1

1 ± 0

8 ± 3

1 ± 1

Ultramarine

Umber

2 ± 3

25 ± 10

Vermilion

86 ± 0

  1. Values are sourced from studies with quantitative SEM–EDX or XRD measurements, or (when in italics) using theoretical formulas as noted (with source references provided) in Table 1