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Table 1 Samples prepared in this study

From: Low-radiation dose XRF excited by MeV protons for cultural heritage samples

 

Thick standard sample for LOD evaluation

Simulated cultural heritage sample

Sample number

#1

#2

#3

#4

#5

#6

Compound or pigment

Copper(II) sulfate pentahydrate (CuSO4·5H2O)

Azurite (Cu3(CO3)2(OH)2)

Smalt (SiO2·K2O·CoO)

Azurite + smalt

Base binding medium

Gelatin (C65H102N18O21)

Support material

(None)

4.5 mg/cm2-thick Japanese hemp paper

Preparation method

Homogenization and pelletization

Painting on paper support and drying

Element of interest

Cu

Cu

Co

Cu and Co

Mass concentration

0 ppm

1000 ppm

10,000 ppm

28%a

3.9%a

Cu 14%a Co 2.0%a

Thickness

≈ 7 mm (cylindrical pellet height)

140 µmb

340 µmb

190 µmb

  1. aConcentration in the pigment-glue mixture after drying
  2. bMeasured whole thicknesses of the paper permeated with the pigment solution after drying