Skip to main content

Table 1 The first oxidation product is Ag2O that by ligand substitution is converted into Ag2S

From: Silver paints in medieval manuscripts: a first molecular survey into their degradation

 

E°/V

ΔG°/kJ/mol

O2 (g) + 4Ag (s) → 2Ag2O (s)

0.43

− 22.42

Ag2O (s) + H2S (g) → Ag2S (s) + H2O (aq)

− 233.26

Ag2O (s) + COS (g) → Ag2S (s) + CO2 (g)

− 256.94

  1. ΔG° value calculated with reference data from [43]