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Table 4 Identification of peaks in the fourth-shot pyrogram shown in Fig. 6 (italics: base peak ion)

From: Synthetic materials in art: a new comprehensive approach for the characterization of multi-material artworks by analytical pyrolysis

No

Peak identification

Main ions (m/z)

1

Acetone

58

2

1,3-Cyclopentadiene

66

3

1,5-Hexadiene

81, 67, 54

4

Benzene

78, 63, 51

5

Acetic acid

60

6

Toluene

91, 65, 51

7

N-ethylacetamide

87

8

Diethylamine

73, 57

9

Ethylbenzene

106, 91

10

5-Hexen-1-ol

82, 67, 54

11

Styrene

104, 78, 63, 51

12

Allylbenzene

117, 103, 91, 77, 65

13

N-propylbenzene

120, 105, 91

14

Benzaldehyde

105, 77, 51

15

(1-Methylethenyl)-benzene

118, 103, 91, 78, 63, 51

16

Allylbenzene isomer

117, 103, 91, 65, 51

17

Cyclohexene

82, 67, 54

18

1-Ethenyl-2-methyl-benzene

117, 103, 91, 73, 63, 51

19

Allylbenzene isomer

117, 103, 91, 77, 63, 51

20

Indene

115, 89, 63, 51

21

1-Butynyl-benzene

130, 115, 102

22

1,2-dihydronaphthalene

130, 115, 102, 77, 67, 51

23

Naphthalene

128, 102, 74, 63, 51

24

1,2-Dihydro-2-methyl-naphthalene

144, 129, 115

25

2-Methylnaphthalene

142, 115, 89, 74, 63, 51

26

1-Methylnaphthalene

142, 115, 89, 74, 63, 51

27

2,6-Diisocyanatotoluene

174, 145, 132, 118, 91, 76

28

1,6-Diisocyanatohexane

99, 85, 69, 56

29

Biphenyl

154, 76, 51

30

2-Naphthol

144, 115, 89, 63

31

Unknown

169, 141, 114, 88, 74, 63

32

Unknown

144, 115, 103, 89, 73, 59

33

Unknown

183, 154, 128, 114, 88, 63

34

1,2-Dihydrophenanthrene

180, 165, 152, 89, 76

35

Phenanthrene

178, 152, 89, 76, 63

36

Oligomer

117, 103, 87, 73, 59

37

2-Phenylnaphthalene

204, 115, 101

38

Oligomer

202, 117, 101, 87, 73, 59

39

Oligomer

175, 117, 101, 87, 73, 59

40

Unknown

261, 232, 204, 129, 102, 77

41

Oligomer

207, 117, 101, 87, 73, 59

42

Oligomer

281, 207, 101, 87, 73, 59

43

Unknown

306, 128, 115, 101, 89, 77