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Table 2 Characteristic parameters of collagen denaturation for historical samples before and after treatment

From: The effect of halloysite nanotubes dispersions on vegetable-tanned leather thermal stability

Sample

Micro DSC (collagen fibrils denaturation)

Overall DSC peak parameters

Population 1

Population 2

Tonset (°C)

Tmax (°C)

ΔH (J·g−1)

ΔT1/2 (°C)

Tmax1 (°C)

%

Tmax2 (°C)

%

Untreated

63.1 ± 1.5

70.9 ± 1.8

17.0 ± 1.9

7.0 ± 0.5

68.2 ± 0.5

49

70.9 ± 0.8

51

HNT-beeswax

65.9 ± 1.7

72.5 ± 0.6

17.2 ± 1.2

5.5 ± 0.3

69.1 ± 1.1

26

72.5 ± 0.6

74

HNT-PEG

64.6 ± 1.0

72.3 ± 0.5

16.1 ± 1.6

3.1 ± 0.8

68.0 ± 0.6

15

72.3 ± 0.5

85

HNT-BNUTO

64.2 ± 2.2

72.4 ± 1.2

18.2 ± 1.4

6.6 ± 0.4

69.1 ± 1.3

30

72.4 ± 1.2

70

  1. The percentage of each collagen population is calculated based on its enthalpy contribution to the overall denaturation enthalpy. At least three measurements with fresh samples were performed for each sample
  2. Uncertainty is the standard deviation
  3. Overall enthalpies of denaturation were corrected based on the mass variation of the sample after treatment