Section | Sample | Cross section | SEM/EDXa | FTIR (transmission) | PyGCMS (Polymeric components) | Inferred composition | ||
---|---|---|---|---|---|---|---|---|
Binding media | Pigment | Otherb | ||||||
Wooden box | Transparent layer at the intersection between boards | – | – | PVAcc | – | – | – | Wooden boards are joined together with neat polyvinyl acetate adhesive |
Wooden box | Unpainted pulp forming the papier mâché | – | – | Cellulose (from wood) PVAcc | – | Gypsum (CaSO4) | – | Unpigmented pulp, mixed with polyvinyl acetate adhesive and gypsum |
Painted/coated papier mâché | Grey paint with transparent coating | One thick layer of dark grey paint, with a highly thinned lighter grey layer on top. An unpigmented, non-fluorescent coating is also present | Ti, Zn, Si, Al, Ca, Fe | p(EA-MMA)d PVAcc | Titanium dioxide (TiO2) Possible carbon black | Calcium sulphate tetrahydrate (CaSO4.4H2O) | Acetic acid Benzene EAe MMAf DEPg EA/MMA dominated pyrogram. | p(EA-MMA)c acrylic dispersion with titanium white (PW6), some zinc oxide and Mars black pigments (PBk11), gypsum. Unpigmented polyvinyl acetate coating |
Painted/coated ropes | Grey paint with transparent coating and glossy, sticky patch | One thick layer of light grey paint. On top, there are two additional layers: an unpigmented and non-fluorescent coating, and an unpigmented, fluorescent layer | Ti, Zn, Si, Al, Ca, Fe | p(EA-MMA)d PVAcc p(nBA-MMA)h | Titanium dioxide (TiO2) | Calcium sulphate tetrahydrate (CaSO4.4H2O) | Acetic acid Benzene EAe MMAf BAi DEPg nBA/MMA dominated pyrogram. | p(EA-MMA)c acrylic dispersion with titanium white (PW6), some zinc oxide and Mars black pigments (PBk11), gypsum. Unpigmented polyvinyl acetate, and unpigmented p(nBA-MMA) coatings |