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Table 1 Summary of the samples in the corpus of analysis

From: An analytical survey of zinc white historical and modern artists’ materials

Brand

Samples

Reference samples

Synthesized ZnO

ZnO nanosmoke synthesized as in Zhang et al. [49]

BrĂĽggemann

Two powders (2020, indirect and direct method)

ZnO manufacturers

KF chemicals

Japan, since 1951

One powder (historical)

Kremer

Germany, since 1977

Two powders (2010 and 2021)

Maastrichtsche zinkwit Maatschappij

The Netherlands, 1870–1989, then acquired by the Vieille Montagne

Four powders of different grades (1907–1989)

Merck

Germany, since 1668

One powder (historical)

Sikkens

The Netherlands, since 1792

One powder (historical)

Vieille Montagne

Belgium, 1837–1989, then Union Minière, today Umicore

Six powders of different grades (1847–1989)

Color manufacturers

Blockx

Belgium, since 1865

Two paint tubes (1976 and 2021)

One titan-zinc white paint tube (2021)

Bocour

US, since 1932

One paint tube (1933–1975)

One titan-zinc white paint jar (1940–1975)

Charvin

France, since 1830

One paint tube (2010)

Craftint manufacturing company

US, 1929–2018

One paint tube (1950s)

Fezandie & Sperrle

US, until 1979

One powder (historical)

Grumbacher

US, since 1905; today, in Chartpark, Inc

Three paint tubes (1950s and two tubes dating back to 1960–1975)

Lefranc

France, 1720–1964, then Lefranc & Bourgeois

One paint tube (1930s)

One paint sample (1950)

One powder with a binder (before 1964)

Lefranc & Bourgeois

France, since 1964

Two paint tubes (after 1964, 2021)

One pastel (after 1964)

Maimeri

Italy, since 1923; in Fila group since 2014

One paint sample from a color chart (1939–1946)

One paint tube (1970s)

Michael harding

US, since 1982

One paint tube (2021)

Old holland

The Netherlands, since 1664

One paint tube (2010)

Permanent pigments

US, 1933–1955

One powder (1933–1955)

One paint tube (1933–1955)

Ripolin

France, since 1888

One paint sample from a color chart (1900)

Sennelier

France, since 1887

Two powders ( after 1887, 2021)

Two paint tubes (after the 1920s and 2021, acrylics)

Talens

The Netherlands, 1889–1969, then Sikkens group, then Akzo Nobel

Two paint tubes (1930s, from the same box: one in good condition, the other yellowed and dried)

Vilhelm Pacht

Denmark, since 1887

One paint tube (1890–1909)

  1. Brands are listed in alphabetical order. The date of production of the samples is indicated between brackets in the column on the right when available