- Research article
- Open Access
A multidisciplinary diagnostic approach preliminary to the restoration of the country church “San Maurizio” located in Ittiri (SS), Italy
© Sammartino et al.; licensee Chemistry Central Ltd. 2014
Received: 7 July 2013
Accepted: 28 January 2014
Published: 10 February 2014
The knowledge of the structure of an artefact, as well as that of its constituent materials and of the hosting environment surely ensures safe guideline for its restoration. Unfortunately, in most cases, a scientific investigation preliminary to restoration is not accomplished due to its high costs and, as a fact, diagnostics is performed only for very precious artworks.
This paper aims to provide a multidisciplinary diagnostic procedure that, although not exhaustive, is rigorous and relatively low cost. It was employed in view of the restoration works on a country church located in Sardinia. A careful inspection of all the architectural elements was carried out in order to highlight structural damages as well as sources of them. One stone and one plaster samples were analysed. The salt content was determined, in two different areas of the church, using three different sampling procedures while only the normed method was used for the determination along the stratigraphy of the sampled plaster. Microclimate monitoring was also carried out.
Water infiltration through the roof was observed. Natural stones and artificial building materials used in the basic architecture resulted to have local source. Both the preliminary “by eye” inspection and the optical microscopy revealed several finishing layers in the investigated plaster samples. The salt content, with some exception, resulted rather low. Microclimate parameters show significant variations only in few areas of the building.
Damage observed inside the oldest part of the Church seems to be mainly related to water infiltrations through the roof and the lack of an effective drainage of the rainwater due to a previous bad restoration. Masonry from one of the newest rooms, showing a strong biodeterioration, as well as some areas inside the nave, revealed a significantly high sulphate content. Building materials (stone and aggregates of mortars) are of local provenance.
Degradation of materials, although accelerated by human factors [1, 2], is unavoidable. Thus, the good practice in conservation, primarily requires an appropriate maintenance plan and, when possible, a placement and fruition suitable to minimize the degrading effects of the environment. This practice clearly requires the knowledge of the materials constituting the artefact and of the physical-chemical parameters characterizing the environment hosting it [3–8]. Italy possesses a huge cultural-historical-artistic heritage; so, unfortunately, due to its costs such practice is not pursued in many cases and, as a consequence, big restoration works become unavoidable when the degrade extent approaches the artefact’s destruction. Also in this phase, excluding very precious artefacts, economic factors let to omit a preliminary diagnostic phase.
In our opinion, the minimum requirements for an effective diagnostic should include a monitoring of the main microclimatic parameters, the knowledge of constituting materials and their eventual forms of degradation, and, for stone buildings (our case), the soluble salt content. Such diagnostic procedure is not so expensive if compared with its beneficial effects in conservation also considering that poor maintenance or bad restoration may cause damage sometimes irreversible and even the loss of the artefact or, at least, a much higher cost for a new restoration.
As a fact, microclimatic conditions and salt content, obviously caused by water rise and/or infiltration are recognized as the main degrading agents [3, 7, 9–13]. Measurement and conditioning of the microclimate are ruled by Italian (UNI) [14–18] and European (EN) norms [19–21] whereas, for salt content, only the measurement procedure is provided . In our opinion, norms concerning microclimate and salt content, should be revised because incomplete and/or too old and not in line with the technological progress. However, such debate is beyond the scope of the present paper. Establishing optimal microclimatic conditions for stone buildings must be considered a simple academic exercise as it cannot be generalized to any environment. On the contrary, evaluation case-by-case, of the microclimate variability is definitely beneficial as its extent and frequency are really responsible for degradation. This statement is irrefutable as proven by the survival of very ancient artefacts in climatically extreme environments such as burial or diving. Certainly, an analytically significant monitoring of a building produces a large amount of data that it becomes difficult to process. Multivariate analysis surely provides a simple overview of data and, consequently, allows us to identify correlations that in turn will help to reduce the monitoring points [23, 24]. The main problems of the UNI 11087:2003 , concerning the salt content analysis, relies on the invasive analytical procedure and the lack of a sampling guideline. Alternative procedures were proposed by various research groups [25–29].
Here we present a multidisciplinary approach to the diagnostic applied in occasion of the restoration of the San Maurizio country Church located in Ittiri (Sardinia, Italy).
Materials and instruments
Ultrapure carbonate and hydrogencarbonate sodium salts, sulphuric acid and referenced standard solutions of anions (chloride, nitrate, sulphate at 1000 ppm, phosphate, fluoride, bromide at 1000 ppm) from MERCK KgaA were used to carry out the IC analyses.
Olympus U-FMT (Japan) transmitted polarised light microscope and Leica MZ6 stereoscopic microscope (Germany) were used for the petrographic characterization of the stone and the plaster samples.
Mineralogic composition of the stone and the plaster samples was also obtained using a Seifert MZIV automatic powder diffractometer.
Structure, morphology and chemical elemental composition of the plaster were investigated using a LEO1450VP Scanning Electron Microscope (SEM) equipped with INCA300 X-ray Dispersive Energy detector (EDS).
The salt content determinations were done using a Ionic chromatograph Compact IC Metrohm equipped with a 250 mm Dionex column AS22 and a 50 mm Dionex precolumn AG22.
Microclimate monitoring was performed using nineteen Hobo data-loggers from Onset Computer Corporation (see Additional file 1: Table S1) and a certified Ebi 20 data-logger from Ebro, (see Additional file 1: Table S1).
Case study: the San Maurizio church
The country church of San Maurizio lies on a hill few kilometres NE of the village of Ittiri (SS), in the historical region of Coros in Logudoro. The church in its original form was built close to a medieval village . In 1571, after the village was abandoned, the church and all its properties were transferred to the Cathedral of Sassari [31, 32]. In 1688, the church was designated as rural church belonging to the City of Ossi. The two rooms located on the north side of the nave date 17th century, while the present sacristy on the south side of the church, was built in the first decade of 20th century, when the church fell under the control of the parish of Ittiri. The small bathroom, on the north side of the nave, was built around 1970.
The church was built using brick, stone and earth according to the types and methods of construction typical of medieval buildings, as observed in Sardinia and in other Italian regions. It consists of a single nave with a barrel vault of squared limestone blocks. The nave consists of four bays slightly decreasing in width toward the altar that gives a perspective effect of greater depth. Presently, the original perception of depth is interrupted by the occurrence of the 19th-century canopy now hosting the statue of the saint. The Church, albeit with homogeneous stylistic features, has small variations: the pilasters are built with stones of alternating colours in the presbytery and of uniform colour in the other three bays. The cornice decoration gets simpler in the first three bays. All these changes support that the construction of the church lasted for several years.
The state of degradation was investigated through the visual inspection of the roof, the bottom of the tiled roof covering, parts of masonry and plaster. This allowed to get a detailed picture of the conservation state of the building, which was pretty evident both outside and inside. (Additional file 1: Figure S1).
The investigation involved all the architectural elements that showed the bigger degradation signs. The architectural elements were evaluated both as a whole and through single details.
The examined roofings are: the one of the nave with an interior barrel vaulted ceiling, the ones of the northward rooms with an interior wooden frameworked ceiling, the one of the sacristy leaning against the southern wall of the nave. The heterogeneity of the constituting materials was also investigated, in particular in order to identify materials used in previous restorations that are not compatible with the original ones.
Petrographic analysis of building stone and plaster
Thin-sections were investigated by means of transmitted polarized light microscopy (PLM), under plain and crossed polars, through the use of magnifications 40×, 100×, 200×, 400×. Polished cross-sections were observed by a stereoscopic microscope through the use of magnification from 6.3× up to 40×. Both thin-sections and polished cross-sections were prepared by vacuum impregnation with low viscosity epoxy resin.
The SEM/EDS analyses on the plaster samples were performed on a polished thin-section. Each layer of the plaster was separated by scalpel with the aid of hand lens. Each of the obtained samples was finely grounded in an agate mortar; a thin layer of the obtained powders was stratified on a satined quartz disk and analysed by XRD.
Sampling design for salt content determination
Efflorescences and moisture stains were observed on the walls inside the church (Additional file 1: Figure S1c) demonstrating the occurrence of water-soluble salt accumulation. Since the environment was too large for a statistical sampling, a rational sampling was preferred to identify the areas of major interest and, on these, statistical sampling was carried out.
During a maintenance work within the niche where the Hobo 10, 12 and 13 data-loggers were located, a painting came to light that restorers defined “frescoe” but really after our investigation it was found to be a “mural painting in tempera”. Anyway, the niche is certainly an area of historical and artistic interest; therefore, it was decided to assess the risk of degradation caused by soluble salt contamination. At this aim, we choose on a vertical profile three sampling points at 0.7, 1.7 and 2.7 m of height, on the left side of the niche (see red squares in Figure 1). A similar vertical profile was chosen on the left side of the pulpit stairs (see red squares in Figure 1) just to have a comparison with the opposite side of the nave. At each height, we sampled salts by three different methods: in situ extraction using Japanese paper (method a); in situ extraction using cellulose pulp (method b); powder sampling according to UNI 11087/2003 (method c) . The relative positions of the sampling points are shown in Additional file 1: Figure S3.
Method a: 50×50 mm pieces of Japanese paper were cut, weighed and placed in plastic dishes labelled with a number and the paper weight. In-situ, they were fully imbibed (about 100 μL) in deionised water (0.1 μS) and placed on the wall; after half an hour they were removed and put back in the plastic dishes. In laboratory, each sample was placed in a 100 ml flask that was brought to volume with deionised water (0.1 μS). Solutions were stirred for about 2 h and then filtered through a 200 nm acetate filter before the analysis.
Metod b: 4.5 g of cellulose pulp were placed inside a 60 mm plastic Petri capsule on the bottom of which 4 small holes were previously done; 28 g of deionised water (0.1 μS) were added in situ and the capsule, fixed by wooden planks and springs, was placed on the wall. The capsule was removed after 24 h. Salt re-extraction from the cellulose pulp was performed, in laboratory, by three successive extractions with deionised water (0.1 μS) using 200 ml in total. After each extraction the cellulose suspension was filtered using a MilliQ apparatus and a 0.45 μm acetate filter, the three solutions were then mixed and analysed.
Method c: samples were taken until 5 mm deep inside the wall on an area such as to obtain an amount of about 0.5 g. The samples were finely ground in an agate mortar and brought to constant weight at 60°C. 100 mg were placed in a 100 ml flask that was brought to volume with deionised water (conductivity 0.1 μS). Solutions were stirred for about 2 hours and then filtered trough a 200 nm acetate filter, before analysis.
All samples were stored at 4°C until pretreatment as well as the sample solutions until the analysis. Measures of conductivity, pH and by ionic chromatography were performed on all the obtained solutions.
The main analytical data for the salt content determination are reported in Additional file 1: Table S2.
Sampling designs for microclimate monitoring
The monitoring campaign began on March 29, 2012 and ended on April 27, 2012. During this period, with the exception of the days during which the sampling of stone, plasters and soluble salts was carried out (8 and 9 April), the Church was closed to the public.
Since the Church is located in a rural area, thus not subjected to pollution caused by road traffic or by industries, the analyses of air pollutants were not planned. The Church is not very frequented, really it is open only during the Feast of St. Maurizio (some days around September 22) and one or two times each month for housekeeping; so, air fluxes were not measured in order to keep low the costs for diagnostic. The only thermohygrometric changes inside the nave therefore occur only from two windows located at a height of about 5 m, about at the centre of the north and east walls (see Additional file 1: Figure S4).
Instruments used for the monitoring are in compliance with the present Norms (see Additional file 1: Table S1).
We adopted a statistical-rational experimental Design, already applied in other buildings (as an example see refs 21–22); it consists in horizontal and vertical profiles covering at the best the building volume and some areas of particular interest. The positions of all used data-loggers are shown in Figure 1 as black diamonds and number or capital letters as label (more details, i.e. height, in Additional file 1: Figures S5-S8). Five data-loggers (HoboG, Hobo8, Hobo9, HoboA and Hobo5) were placed on a horizontal profile, starting from the main entrance and ending on the altar, at a height of about 4 m and a distance of about 5 m from each other (Figure 1 and Additional file 1: S5). Four data-loggers (Ebro, Hobo11, HoboL and Hobo7) were placed on a vertical profile in the middle of the nave, starting at 0.25 m from the floor and ending near the roof, at a distance of about 2.5 m from each other (Figure 1 and Additional file 1: Additional file 1: S5). A shorter vertical profile (Hobo13, Hobo10 and Hobo12) was drawn inside a niche containing a mural painting, starting at 0.20 m from the floor with points spaced about 2 m (Figure 1 and Additional file 1: S6). One data-logger was placed inside each of the four rooms around the nave, all at an eight of 0.24 m (Figure 1). The last three data-loggers were placed on the pulpit, on the stairs of the pulpit and inside a niche (Figure 1 and Additional file 1: S7). A data-logger was placed outdoor (see Additional file 1: Figure S8) to monitor the local macroclimate.
Among the different possible methods of data treatment, the Box-Whiskers graphs were chosen since they provide the main information on the differences recorded throughout the monitoring period by each data-logger, i.e. median values, 5°, 10°, 25°, 90°, 95° percentiles and spreads. Moreover, in order to highlight the daily maximum variation two graphs showing the average Temperature and Relative Humidity measured at 6-hour intervals, along the vertical profile are also reported. Original data are shown, as run-plots, in Additional file 1: Figure S9. Furthermore, Additional file 1: Figure S10 compares standard deviation (SD) of T and RH data measured by all indoor sensors, during the whole monitoring period, with the corresponding parameters measured by the outdoor sensor, while, Additional file 1: Figure S11 compares the percentage Standard Deviation calculated for T and RH. Such graphs, not only evidence the insulation degree of the building but also the extent and frequency of the variations that, as said in the background, are mainly responsible for degradation.
Structural building inspection
The roofing of the main pitch covering the nave: it has several broken tiles that bring on seepages of water. The tiled roof covering rests directly on the vault extrados with a thin layer of earth in between. The tiles are positioned on some fragments of brick that make the profile regular and formed a hollow space together with the vaulted structure.
The tiled roof covering, part of the northward jutting rooms roofing, rests on a wooden structure and proceeds in a continuous way over the masonry barrel vault of the nave. The heterogeneous structure is rather unusual on a structural level. Nevertheless, it comes out uniform thanks to the tiled roof covering that proceeds uninterruptedly along the gently curved path of the pitch and of the barrel vault.
The tiled roof covering of the sacristy room consists of plain roofing tiles. The single pitched roof pours water out along the fall line which is parallel to the longitudinal axis of the nave. This pitch interferes with the church projection that coincides internally with the niche wall where a painting was located. However, the solution of the insertion between the sacristy and the church caused seepages of water in the point of contact between the two spaces. This happened because the church projection formed a “plug” that prevents the water from draining regularly. As time goes by, this problem resulted in internal seepages of water causing an advanced degradation of the plaster underneath the painting.
Building work: the external brickwork shows an advanced degradation especially in the northern and western façades. In these façades, the plasters are so friable that an integral preservation is not possible. Cement patches evidenced a previous restoration work not compatible with the type of building. The deterioration was due to the seepages of water coming from the roof and to the humidity coming from the external surface. During the excavation work around the building, old drains emerged. In the beginning, these drains had the function of carrying the rainwater and the groundwater to the side of the church.
The building stone
Optical Microscope (OM) observations on the thin-section and the polished cross-section show that the plaster sample is made up of two main parts: the inner plaster base (19 mm thick in the cross-section) and the finishing layers (maximum thickness 2 mm in the cross-section (Figure 3 and Additional file 1: Figure S12).
The plaster base consists of 40-45% in volume of aggregate with a grain size in the field of average-coarse sand (0.1-10 mm), moderate to scarce sorting, variable roundness (ranging from angular to sub-rounded) and average to low sphericity (Figure 4 (a-b)). The aggregate is homogeneously distributed and no preferred orientation of the grain was discerned. The aggregate is composed of lithic fragments and monocrystalline grains. The prevalent lithologies are dacite to rhyolite igneous rocks showing porphyric textures and groundmass varying from microcrystalline to holoyaline, pyroclastic volcanic rocks with eutaxitic textures and holoyaline volcanic scoria; carbonate rocks (bioclastic calcarenites), quartzites. Monocrystalline grains consist mostly of oligoclase andesite plagioclase and subordinately of quartz, calcite, biotite, magnetite, iron hydroxides and microcline. Fossil fragments of echinides and bivalves were also found. The mineralogic-petrographic composition of the aggregate supports a provenance of the raw materials from the main volcanic and sedimentary lithologies outcropping in the surroundings of the San Maurizio church .
The binder is a lime-based (calcitic), nearly homogeneous, micritic sometime microsparitic matrix, although some sparse uncarbonated rounded lumps of lime were also observed. The volume occupying by the lime binder is about 50 vol. %, the porosity is less than 20% on the total volume of the sample and is due to voids occurring in the binder, in the lithic fragments of the aggregate and sporadically due to cracks at the grain-binder boundary. In its inner part the plaster base reveals a distinct layer, showing a lighter coloured matrix, which seem also distinguished by the finer grain size of the aggregate, a minor content of volcanic lithic fragments and a higher porosity in the binder. Such contrasting features could indicate the occurrence of an older plaster layer, different for, aggregate composition, binder concentration and porosity, which probably suffered carbonate dissolution-reprecipitation of the lime binder matrix.
Different finishing layers were observed in the top-coat. The plaster base is directly covered by a thin white limewash, which is overlain by two paint layers, the innermost one, pink in colour, with pigment particles (ochre and iron oxides/hydroxides) mixed with carbonate binder, and the outermost showing a lighter yellowish coloration probably due to a lower concentration of pigment particles.
At the top of the paint strata a white layer, about 1 mm thick, is observed (Figures 3 and 4 and Additional file 1: Figure S12). It is consists of several continuous finishing coats of the same lime-based paint. A definite detachment separates the top white paint layer from the innermost pink and yellowish layers.
Mineral phases identified by XRD for the plaster sample
Salt content determination inside the church nave
Two sampling vertical profiles were chosen inside the nave of the church, on opposite side. One profile (on left side wall facing the main altar, see red squares on the map in Figure 1) was located inside a niche containing a wall painting, being a position of particular interest. Three different sampling methods (see the relative sampling positions in Additional file 1: Figure S3) were adopted: One (invasive), according to Italian norm UNI 11087/2003  requires the sampling of powder from the substrate, while the other two procedures (non invasive) base on the in-situ extraction of water soluble salts using Japanese paper and cellulose pulp.
However, data obtained by the UNI method, that surely must be considered the more accurate, indicate a worrying sulphate concentration in the colder right wall, (i.e. higher than 3% w/w for the lower sampling point (see Additional file 1: Table S3).
During the monitoring campaign the church was closed to the public; so, all the observed variations are only related to the macroclimate changes and can be useful to evaluate the insulation level of the building and the spontaneous thermohygrometric conditions. Additional file 1: Figure S9 provides the trends of Temperature (T) and Relative Humidity (RH) registered in all the measuring points (indoor and outdoor) throughout the monitoring period. It can be noticed a general good insulation inside the nave; actually, as better evidenced in the Box-Whisker plots (Figure 8 (a-b)), the T and RH fluctuations for all the indoor sensors result half, or lower than half, of the external ones. Such features are also evident in Additional file 1: Figure S10, where the standard deviation (SD) of T and RH data measured by all indoor sensors, at each ten minutes interval, throughout the whole monitoring period, are compared with the corresponding run-plots of the outdoor parameters (HoboD). Additional file 1: Figure S11, where the percentage standard deviation of T and RH are compared, shows that RH fluctuations are larger than those of T.
The highest RH values and the lowest RH spread were recorded inside the room monitored by HoboC (Figure 8b), in agreement with its north-facing position. Slightly lower RH values were registered in the room monitored by HoboH (also north-facing), and in the point monitored by Hobo13 (in south-facing position but at the minimum sampled quote, i.e. about 0.2 m). No enough significant variations result for the horizontal profile along the nave (Figure 8c and d), while small but significant changes are evidenced along the vertical profile in the middle of the church (about 1°C of T and 3% of RH, Figure 8 (e-f)). The largest thermohygrometric variability is observed along the vertical profile inside the niche containing the wall painting (more than 1°C of T and about 14% of RH, Figure 8 (g-h)) and among the four rooms around the church nave (about 2°C of T and about 19% of RH, Figure 8 (i-l)). The decreasing RH trend from bottom to top observed inside the niche suggests that water enters by rising damp (being the exterior wall directly in contact with the ground) rather than by infiltration through the roof. As regards the four rooms around the nave, data are congruent with their orientation and sun exposure.
The Church suffers for a poor and/or bad maintenance that let to structural damage. Certainly the placement in direct contact with the ground and the burying of the original channels for rainwater drainage involve a rising damp and consequently salt accumulation within the walls. Petrographic and XRD analyses have been particularly helpful for the choice of materials to be used for the restoration, i.e. locally sourced stones for the oldest parts of the church and for mortar aggregates. The patina effect was obtained by a suitable mixing of lime and local sand, choice to get the color of the original surfaces. The plaster sample collected from the room monitored by Hobo I, presents serious biodeterioration and high sulphate content in the outermost layers. The finishing layers, at least three, two of which pigmented, are based on lime; plaster base is made up of lime and an aggregate of local raw materials. A worrying sulphate content was revealed also in the lower sampling point of the vertical profile inside the niche. Further analyses after restoration are suggested in order to assess the need for desalination treatment.
The microclimate monitoring revealed good insulation with indoor thermohygrometric fluctuations resulting half or less than half of the corresponding outdoor ones. T and RH variations are almost null along the horizontal profiles, limited but significant along the vertical profile in the middle of the nave, whereas the higher variability resulted along the vertical profile inside the niche containing the wall painting and among the rooms located around the nave. During the monitoring period, along the vertical profile, the maximum variation of T and RH occur at 3 pm (2°C and less than 10%, respectively). The maximum RH variation coincides with the maximum tolerance foreseen by the UNI 10829 whereas no indication is available for temperature. The number of sensors for a future continuous monitoring could be greatly reduced although a second campaign covering the four seasons would be needed.
The restoration work mainly foresees: a) the maintenance of an hollow space between the ceiling and the roof in order to minimize the vertical thermohygrometric fluctuations; b) the complete overhaul of the roofing through substitutions and/or integrations in the tiled roof covering together with all that is necessary to prevent seepages of rainwater; c) the realization of a drainage to reduce the supply of water which stagnates on the ground close to the wall of the building; d) the removal of not original and degraded plasters from the walls and the subsequent restoration through the application of a natural lime-based mortars with aggregates from local quarries; e) the preservation of the wall heterogeneity and the patina effect.
Thanks to Valeria Cuzzilla, Natalia Macro and Martina Tornese that contributed to the work as some parts constituted the internship job for their bachelor's degree.
- Cooke RU, Gibbs GB: Crumbling Heritage? Studies of stone weathering in polluted atmospheres. Atmos Environ. 1994, 28 (7): 1355-1356. 10.1016/1352-2310(94)90284-4.View ArticleGoogle Scholar
- Sandrolini F, Franzoni E, Sassoni E, Diotallevi PP: The contribution of urban-scale environmental monitoring to materials diagnostics: a study on the Cathedral of Modena (Italy). J Cult Herit. 2011, 12 (4): 441-450. 10.1016/j.culher.2011.04.005.View ArticleGoogle Scholar
- Lankester P, Brimblecombe P: Future thermohygrometric climate within historic houses. J Cult Herit. 2012, 13 (1): 1-6. 10.1016/j.culher.2011.06.001.View ArticleGoogle Scholar
- Francaviglia N, Lombardo A, Caramanna S: Conservation work on an ancient Sicilian processional banner: preliminary analyses and in situ restoration. Procedia Chem. 2013, 8: 109-116.View ArticleGoogle Scholar
- Lembo F, Marino FPR, Ambrosecchia N: Sustainability in civil engineering: integrated mix of some non-invasive sensing techniques for conservation and restoration of historical buildings and frescoes. Procedia Eng. 2011, 21: 446-456.View ArticleGoogle Scholar
- Bersani D, Campani E, Casoli A, Lottici PP, Marino IG: Spectroscopic study of the degradation products in the holy water fonts in Santa Maria della Steccata Church in Parma (Italy). Anal Chim Acta. 2008, 610 (1): 74-79. 10.1016/j.aca.2008.01.041.View ArticleGoogle Scholar
- Pérez-Alonso M, Castro K, Álvarez M, Madariaga JM: Scientific analysis versus restorer’s expertise for diagnosis prior to a restoration process: the case of Santa Maria Church (Hermo, Asturias, North of Spain). Anal Chim Acta. 2004, 524 (1–2): 379-389.View ArticleGoogle Scholar
- Bianchin S, Favaro M, Vigato PA, Botticelli G, Germani G, Botticelli S: The scientific approach to the restoration and monitoring of mural paintings at S. Girolamo Chapel – SS. Annunziata Church in Florence. J Cult Herit. 2009, 10 (3): 379-387. 10.1016/j.culher.2008.11.002.View ArticleGoogle Scholar
- Valenza JJ, Scherer GW: A review of salt scaling: II mechanisms. Cem Concr Res. 2007, 37 (7): 1022-1034. 10.1016/j.cemconres.2007.03.003.View ArticleGoogle Scholar
- Petkovic J, Huinink HP, Pel L, Kopinga K, van Hees RPJ: Salt transport in plaster/substrate layers. Mater Struct. 2007, 40 (5): 475-490. 10.1617/s11527-006-9151-7.View ArticleGoogle Scholar
- Plattner SH, Reale R, Visco G, Papa MG, Sammartino MP: Proposal of a new analytical procedure for the measurement of water absorption by stone. Preliminary study for an alternative to the Italian technical normative NORMAL 07–81. Chem Cent J. 2012, 6: 62-10.1186/1752-153X-6-62.View ArticleGoogle Scholar
- Eric D, Clifford Price A: Stone Conservation, An Overview of Current Research. 2010, Los Angeles, USA: Getty Publications, ISBN ISBN: 978-1-60606-046-9, SecondGoogle Scholar
- Ponziani D, Ferrero E, Appolonia L, Migliorini S: Effects of temperature and humidity excursions and wind exposure on the arch of Augustus in Aosta. J Cult Herit. 2012, 13 (4): 462-468. 10.1016/j.culher.2012.01.005.View ArticleGoogle Scholar
- UNI 10586–1997: Condizioni climatiche per ambienti di conservazione di documenti grafici e caratteristiche degli alloggiament. 1997, Rome: Ente Nazionale Italiano di UnificazioneGoogle Scholar
- UNI 10829–1999: eni di interesse storico artistico - Condizioni ambientali di conservazione – Misurazione ed analisi. 1999, Rome: Ente Nazionale Italiano di UnificazioneGoogle Scholar
- UNI 10969–2001: Beni culturali - Principi generali per la scelta e il controllo del microclima per la conservazione dei beni culturali in ambienti interni. 2002, Rome: Ente Nazionale Italiano di UnificazioneGoogle Scholar
- UNI 11120–2004: Beni culturali - Misurazione in campo della temperatura dell’aria e della superficie dei manufatti. 2004, Rome: Ente Nazionale Italiano di UnificazioneGoogle Scholar
- UNI 11131–2005: Beni culturali - Misurazione in campo dell’umidità dell’aria. 2005, Rome: Ente Nazionale Italiano di UnificazioneGoogle Scholar
- EN 15758–2010, Committee CEN/TC 346: Conservation of cultural property. Procedures and instruments for measuring temperatures of the air and the surfaces of objects. 2010, Brussels: European Committee For StandardizationGoogle Scholar
- EN 15757–2010: Conservation of Cultural Property - Specifications for temperature and relative humidity to limit climate-induced mechanical damage in organic hygroscopic materials. 2010, Brussels: European Committee For StandardizationGoogle Scholar
- EN 15759–1:2011, Committee CEN/TC 346: Conservation of cultural property - Indoor climate - Part 1: Guidelines for heating churches, chapels and other places of worship. 2011, Brussels: European Committee For StandardizationGoogle Scholar
- UNI 11087–2003: Beni culturali - Materiali lapidei naturali ed artificiali - Determinazione del contenuto di sali solubili. 2003, Rome: Ente Nazionale Italiano di UnificazioneGoogle Scholar
- Visco G, Plattner SH, Fortini P, Di Giovanni S, Sammartino MP: Microclimate monitoring in the carcer Tullianum: temporal and spatial correlations and gradients evidenced by multivariate analysis; first campaign. Chem Cent J. 2012, 6 (Suppl 2): S11-10.1186/1752-153X-6-S2-S11.View ArticleGoogle Scholar
- Visco G, Plattner SH, Fortini P, Sammartino MP: Second campaign of microclimate monitoring in the carcer Tullianum: temporal and spatial correlation and gradients evidenced by multivariate analysis. Chem Cent J. 2012, 6: 104-10.1186/1752-153X-6-104.View ArticleGoogle Scholar
- Petkovic J: Moisture and ion transport in layered porous buildings materials: a Nuclear Magnetic Resonance study. 2005, Printed by PrintPartners Ipskamp, Enschede (Netherlands): PhD Thesis, Eindhoven University of Technology, ISBN 90-386-2151-5Google Scholar
- Olmi R, Bini M, Ignesti A, Priori S, Riminesi C, Felici A: Diagnostics and monitoring of frescoes using evanescent-field dielectrometry. Meas Sci Technol. 2006, 17 (8): 2281-2288. 10.1088/0957-0233/17/8/032.View ArticleGoogle Scholar
- Maurício AM, Pacheco AMG, Brito PSD, Castro B, Figueiredo C, Aires-Barros L: An ionic conductivity-based methodology for monitoring salt systems in monument stones. J Cult Herit. 2005, 6 (4): 287-293. 10.1016/j.culher.2005.01.003.View ArticleGoogle Scholar
- Tropea C, Sammartino MP, Visco G: Preliminary study to set up a non destructive in Situ method to monitor soluble salts content in stone materials; the usefulness of a multivariate approach. Curr Anal Chem. 2010, 6 (1): 94-99. 10.2174/157341110790069565.View ArticleGoogle Scholar
- Marabelli M, Mannaioli A, Sammartino MP: Invasive and Not Invasive Analysis of Soluble Salts in Stones; Look For Correlation in the Case Study of the Todi Cathedral Floor. Application of Multivariate Analysis and Chemometry to Cultural Heritage and Environment (CMA4CH Taormina 26–29 Settembre 2010). Edited by: Marco V. 2010, Torino, Italy, ISBN 9788875Google Scholar
- Day J: Villaggi abbandonati della Sardegna dal trecento al settecento. 1973, Parigi: InventarioGoogle Scholar
- Vulpes G: Ittiri Monumenti di parole Monumenti di pietra. 1989, Coop. Lavoro e Società a r. l: SassariGoogle Scholar
- Pasquale T: Codex diplomaticus Sardiniae. Monumenta historia patriae. Tomo II: Torino, 1861–1868. doc. XXXI, pag. 54Google Scholar
- Funedda A, Oggiano G, Pasci S: The Logudoro basin: a key area for the Tertiary tectono-sedimentary evolution of North Sardinia. Boll. Soc. Geol. It. 2000, 119: 31-38.Google Scholar
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