The origins of mural painting in Ancient Peru: archaeometric preliminary study of the Ventarrón mural paintings, Valle de Lambayeque
© Wright et al. 2015
Received: 5 December 2014
Accepted: 10 August 2015
Published: 12 October 2015
Since 2007, the research led on the Huaca Ventarrón site has allowed investigators to discover outstanding wall paintings. These murals are one of the oldest examples of this artistic expression in the Andean area and American continent (4000 BP). Analyses have given indications on the materials and techniques used by the first painters, ancestors of a long pictorial tradition.
Thanks to an archaeometric approach, combining observations and analysis (Optical Microscopy (OM), Scanning Electron Microscopy and Energy-dispersive X-ray Spectroscopy (SEM–EDS), X-ray Fluorescence (XRF) and Fourier Transform Infrared Spectroscopy (FTIR)), it was possible to characterize the colorant materials used in the two constructive sampled phases. These materials are mineral pigments, iron oxides, clays and natural earth, mixed in order to create a wide chromatic scale.
Through this research we were able to obtain the first analytical data concerning such ancient mural paintings. It was very useful to comprehend the emergence of this artistic expression in Peru. These results open new research perspectives as well about the origins of Prehispanic pictorial technology as about conservation of wall-paintings in earthen architecture.
KeywordsPigment Color technology Mural painting Archaeometry Peru
This temple was built in three phases, one on top of the other. Until today ten architectonic renovations have been identified. The oldest phase was built over a rocky promontory marking the sacred character of its beginning as well as the orientation and distribution of the architectonic design. The broad Lambayeque Valley and the Reque River were visually controlled from the top of the temple. In this high area was placed the first ritual fire. On a wall at the south side of the fire, a representation of two fishes face to face in high relief without polychromy was discovered.
On the southwest sector of the temple, there are remains of paint left on the eastern wall. This painting has a red background, a gray frame and two white vertical strips. Furthermore, a hall was built in the first room of this area with a singular cruciform plan. It is similar to the classic Andean cross or “chacana” with wall paintings in white, black, gray, red and yellow.
Finally, in order to build the third phase, which was called Green Temple, the inside of the Red-White Temple was completely filled. Vertically a retaining wall was built above the platform, slightly retracted from the previous facade and supported by a great buttress system. Over the atrium was built a new central room, which exterior walls were painted with green and white strips (Fig. 2).
While the wall painting in Ventarrón has already been investigated from an iconographic point of view, in this research the approach will be archaeometric. The objective of this analytical methodology is to characterize the materials and techniques used by the artisan painters of this site, and then to rebuild the “chaîne opératoire” or pictorial technology from the extraction of the raw colouring materials until the finished mural. Besides Ventarrón being the oldest example of wall painting in the present Peruvian territory, this study will allow us to understand the origins of this artistic expression and the emergence of the artisanal practices developed later through the Prehispanic history.
First, samples were observed by stereomicroscopy. The selected ones were prepared in epoxy resin, cut in cross-sections in order to be studied with optical microscopy (OM)1 at 40 and 100 magnifications. This first step of observation allowed to get information about the number of pictorial layers, its set of features and its thickness. Then the 20 samples were analyzed with X-ray fluorescence (XRF)2. The data obtained allowed us to define the elemental composition of each pictorial layer and infer the chromogenic element in each sample. This analysis also enabled us to characterize trace elements, useful to the understanding of the geological origins of the minerals. After this, so as to complete and confirm all this data, a sample selection was analyzed with Fourier Transform Infrared Spectroscopy (FTIR)3. This technique gave us structural information, useful to the identification of clays and natural earth often part of colorant mixtures composition. Finally, three samples (Phase 2/M2/Black, Phase 3/M4/White, Phase 3/M7/Green), which identifications were not completely known, were observed and analyzed by Scanning Electron Microscopy and Energy-dispersive X-ray Spectroscopy (SEM–EDS)4.
Thanks to this protocol combining observation techniques and elemental and structural analysis, it was possible to answer to the problematic established about the wall painting in Ventarrón, and to achieve new results about materials and techniques used by the craftsmen.
Finally the XRF analyses have enabled to determine the presence of many trace elements as minor compounds which belong to metallic inclusions of nickel (Ni), copper (Cu), zinc (Zn) and arsenic (As) and rare earth element of yttrium (Y) in each sample (Fig. 7).
The results from the three samples taken from this phase, allowed us to demonstrate that the green and white paint represent just one very thin pictorial layer (from 10 to 30 μm thickness), with thin homogenous grain (5 μm on average) just as Phase 2 (Fig. 4).
Furthermore, similarly to Phase 2, it was possible to demonstrate by XRF analysis the presence of many trace elements as minor elements which correspond to metallic inclusions of nickel (Ni), copper (Cu), zinc (Zn) arsenic (As) and rare earth element of yttrium (Y) (Fig. 4).
This archaeometric research allowed us to understand that all the coloring materials used in Ventarron’s wall painting are natural pigments of mineral origin. The fineness and homogeneity of the granulometry indicate a carefully prepared work and a controlled technique. Furthermore, besides the two repainting identified, each constructive phase presents just one pictorial layer with thin thickness (10–35 μm average) which can be consider as a temporal indicator of the occupation of each building.
The results indicate the presence of illite and calcite in the white coloring mixture. The red and yellow chromogenic elements correspond to iron oxides such as the black—which structural complementary composition has to be completed—while the green belongs to green earth. All these are mixed with clay—illite—and associated to a high calcium concentration, possibly in calcite form. However, we can wonder if this association is intentional or fortuitous. In fact, calcite is usually used as additive for pigments due to its low colorant capacity, its opacity and its refractive index, which influences over the painting rheological properties, impermeability and conservation [4, 5]. Moreover, previous researches, especially in the Moche art wall painting in the Peruvian north coast [6, 7] suggest that the artisans mixed the white preparation to red, yellow and black preparations, in different and controlled proportions in order to get a wider chromatic range. Taking into account the chromatic palette used in Ventarrón we assume this mixture was intentional and had an esthetic and technical character.
On the other hand, the knowledge of pigments and additives leads us to wonder about the presence of organic binder, adjuvant usually added to the coloring mixture to improve the viscosity and adhesiveness to the wall surface. Nevertheless the experimentations realized, particularly in FTIR, did not allow to evidence this kind of product.
Regarding the interest of such preliminary data, new structural analysis (by FTIR or Raman spectroscopy for instance) should be done to precise the composition of the paint layers, the mineral structure of the iron oxides and green earth, such as the presence of organic materials.
Thanks to the XRF experimentations, it was possible to characterize the same trace elements in each sample. These minor compounds are considering as indicative of the geological provenance of the raw materials. Being identical in each sample it might indicate a common origin (at least close) of the coloring materials. The presence of these markers as well as the similarity between the two white samples (Fig. 6) in the two constructive phases analyzed suggest a temporary continuity in the use of the materials and its geological origin.
This data proposes new research perspectives, particularly about quarry locations or veins of pigments used by the craftsmen.
The Ventarrón murals are one of the oldest wall painting examples in the Andean area and the American continent and this archaeometric study is the first one that has focused on such ancient polychrome vestiges, distinguishing the important nature of the conclusion reached.
The results contributed to identify the materials and techniques used since early periods. This information is useful to apprehend the emergence of this artistic expression and to better understand the first artisan painters, ancestors of a long pictorial tradition developed up until the Spanish Conquest.
This kind of research also provides progress in conservation work. Indeed, according to the analyzed data, the treatments applied can be reevaluated and adapted, improving the murals protection conditions.
Finally, this research illustrates the interest and significance of archaeometry, arguing its systematization to develop archaeological problematic as well as heritage conservation issues in Peru.
The OM observations were proceeded at the Dating Laboratory of the "Universidad Nacional de Ingenieria" (UNI) in Lima, Peru.
The Archaeometry Laboratory, Faculty of Physics of the "Universidad Nacional Mayor de San Marcos" (UNMSM) in Lima by Dr. Jorge A. Bravo. The portable equipment used (model XR—100 CR) is composed of an X-ray tube (Eclipse II by AMPTEK-Oxford) with an Ag-anode, and an AMPTEK thermoelectrically cooled Si-PIN X-ray detector. Experimentations were realized in a 90° configuration with the following parameters: 30 kV–0.1 mA.
The Archaeology Laboratory of the "Pontificia Universidad Católica del Perú" (PUCP) in Lima. An equipment Bruker Tracer III-SD was used, with the following parameters: 45 kV–11.30 μA.
The FTIR analysis were proceeded at the "Centre de Recherche et de Restauration des Musées de France" (C2RMF), Palais du Louvre, Paris; with a Spectrometer FTIR Perkin Elmer Spectrum 2000, by mid-infrared transmission spectroscopy using a micro diamond cell.
The SEM-EDS observations and analysis were proceeded at the "Centre de Recherche et de Restauration des Musées de France" (C2RMF), Palais du Louvre, Paris. The equipment used is a FEI XL30 CP associated with a Silicon Drift Detector X-MAX 50 anceladod an AZtec Energy Advanced analytic platform. The tension applied was 20 kV in a controlled pressure (CP) configuration. The images were made combining secondary electrons (SE) (such as Everhart and Thornley detector) and back-scattered electrons (BSE).
VW and IAM coordinated the study. VW realized the observation protocol at the UNI, the XRF analysis at the PUCP and those by FTIR at the C2RMF. EL performed the analyses by SEM-EDX at the C2RMF. VW collected samples in Ventarrón assisted by IAM. VW edited and prepared the first version of the text. All authors read and approved the final manuscript.
This research was possible thanks to the support of Dr. Luis Jaime Castillo, Vice-minister of Culture of Peru and director of the Archaeological laboratory of the PUCP in Lima, who kindly facilitated the access to the XRF equipment. We also thank Dr. Michel Menu, Director of the Research Department of the C2RMF in Paris, who allowed us to work in collaboration with this laboratory. Special thanks to the crew of Ventarrón for their kindness and hospitality; to Aldo Watanave for his help during the XRF measurements in PUCP; and to Gianella Pacheco and Charlotte Quinquis for their help editing this article.
Compliance with ethical guidelines
Competing interests The authors declare that they have no competing interests.
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